Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs.
نویسندگان
چکیده
A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(ii) gave IMP-18 - a 3D MOF incorporating Si-O-Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(ii).
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ورودعنوان ژورنال:
- Chemical communications
دوره 53 93 شماره
صفحات -
تاریخ انتشار 2017